Green and Sustainable Organic Synthesis (CO2
Accounts and Rapid Communications in Chemical Synthesis
Furthermore, we have disclosed the first oxytrifluoromethylation of allylamines with carbon dioxide (CO2) to synthesize important CF3-containing 2-oxazolidones via Cu-catalysis It is also the first time to utilize CO2, a nontoxic and easily available greenhouse gas, to tune the difunctionalization of alkenes from amino- to oxy-trifluoromethylation. Of note, this multi-component reaction is highly chemoselective, regioselective and diastereoselective under redox-neutral and mild reaction conditions.
Thieme E-Books & E-Journals - Synthesis / Issue
19.D.-G. Yu, F. de Azambuja, T. Gensch, C. G. Daniliuc, F. Glorius*, The C–H Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIII-Catalysis. Angew. Chem. Int. Ed.2014, 53, 9650. (Highlighted by Synfacts 2014, 10, 1023)
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The key feature of the synthesis involves the high stereoselective photoelectron-transfer-promoted cyclization of the strained α-trimethylsilylmethylazetidine moiety to the tethered π functionality.
Benzyl Ethers - Organic Chemistry Portal
A preliminary in vitro cytotoxicity evaluation of the synthesized thia analogues of calothrixins displayed promising potential against cancer cell cultures.
Mendoza Lab - Stockholm University
In recent years, the MBH adducts and their derivatives such as acetates and bromides have served as efficient synthons for the synthesis of bioactive compounds including natural products.
Attachment of Boc group to NH2 vs OH..
32.Z.-J. Shi *The “Welding” Technology in Organic Synthesis. Sci. Tec. Rev.2010, 28, 29. (Invited review)