Synthesis of conjugated polymers for organic solar cell ..

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Hsu CS, Synthesis of conjugated polymers for organic solar cell ..

Synthesis and characterization of three small band gap conjugated polymers for solar cell ..

CHEMISTRY - University of Washington

It describes the synthesis, properties and applications of the main classes of conjugated polymers as well as gives details on design principle for materials for solar cells applications.

Organic Solar Cells - Theory and Practice | Coursera

A series of simple phenothiazine-based dyes have been synthesized, in which a cyanoacrylate acceptor directly attached to the C(3) position of phenothiazine, and an additional linear electron-rich (4-hexyloxy)phenyl group at C(7) on the opposite side of the acceptor, and an alkyl chain with different length at N(10) of the phenothiazine periphery are presented. The dye molecules have a linear shape which is favorable for the formation of a compact dye layer on the TiO2 surface, while their butterfly conformations can sufficiently inhibit molecular aggregation. Moreover, the structural features of (4-hexyloxy)phenyl donor moiety at the C(7) position of phenothiazine extends the π-conjugation of the chromophore, thus enhancing the performance of dye-sensitized solar cells (DSSCs). Moreover, the alkyl substituents with different chain length at the N(10) atom of phenothiazine could further optimize the performance through completely shielding the surface of TiO2 from the I/I3- electrolyte and subsequently reducing the leakage of dark current. Under simulated AM 1.5G irradiation, the PT-C6 based DSSC produces a short-circuit photocurrent of 15.32 mA cm–2, an open-circuit photovoltage of 0.78 V, a fill factor of 0.69, corresponding to a power conversion efficiency (PCE) of 8.18%, which exceeds the reference N719 (7.73%) under identical fabrication conditions. Notably, the designed molecular structure represents the highest photovoltaic conversion efficiency value when compared with other reported phenothiazine-derived dyes.

Macromolecules 2012, 45, 607-6326 Synthesis of Conjugated Polymers for Organic Solar Cell Applications, Y.-J.
Synthesis of conjugated polymers with complex architecture for photovoltaic applications

Staff Profile - City University of Hong Kong

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Synthesis of two conjugated polymers ..

Two donor-acceptor alternating conjugated copolymers were synthesized as the donor materials of the active layer in polymer solar cells via Stille coupling reaction. Both copolymers consisted of dithienosilole as the donor unit and nonfluorinated 2,1,3-benzooxadiazole or fluorinated 2,1,3-benzooxadiazole as the acceptor unit. The nonfluorinated polymer and fluorinated polymer were designated as P1 and P2, respectively. The structures of copolymers were confirmed by FT-IR, 1H NMR, and 13C NMR. Optoelectronic properties of the polymer were investigated and observed by UV-vis spectrum, photoluminescence spectrum, and cyclic voltammetry. Both polymers exhibited a panchromatic absorption ranging from 300 nm to 1100 nm and displayed low band gaps of 1.46 eV and 1.42 eV, respectively. Both of the synthesized materials were used as the donor material in the bulk heterojunction (BHJ) solar cells and then power conversion efficiency (PCE) measurements were conducted in different weight ratios of the polymer:PC61BM blends.

The stability of the conjugated polymer-fullerene solar cell ..

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