chlorine gas is led into a flask containing elemental sulfur
Sulfur dichloride - Sciencemadness Wiki
To ensure pure first-order kinetics, sulfur mustard is predissolved in a polar organic solvent, and its concentration is kept low in solution so that the rate of the reverse reactions become negligible compared to kw. The overall reaction—the formation of dithioglycol and 2 HCl—can be described as a quasi-monomolecular process with first-order kinetics. The rate constant for the hydrolysis of sulfur mustard, as determined by acid production, is markedly dependent on temperature and the presence of chloride ion, which retards the hydrolysis rate without altering the reaction products. The retardation of hydrolysis by added chloride is consistent with the reversibility of the activation step to cyclic sulfonium ion. The rate of hydrolysis is not pH dependent and is not altered by metal ions.
This reaction may also produce disulfur dichloride
Sulfur dichloride is a . It has a strong . It is a common sulfur chloride. It reacts with water to make and . When it is old, it might have some in it. It reacts with to make .
Disulfur Dichloride - Paperplane
Also called ETHYLENE DICHLORIDE, or 1,2-DICHLOROETHANE, a colourless, toxic, volatile liquid belonging to the family of organic halogen compounds and having an odour resembling that of chloroform. It was formerly important as a solvent and as a raw material for making ethylene glycol and polysulfide rubbers, but now it is principally used for making vinyl chloride and as a component of tetraethyllead anti-knock formulations for gasoline. Ethylene chloride is produced by the reaction of ethylene and chlorine; it is denser than water and practically insoluble in it. It is an effective solvent for fats, waxes, greases, and numerous other organic compounds, but its use as a solvent has been largely discontinued in favour of tetra-chloroethylene.
Sulfur monochloride in organic synthesis - IOPscience
Sulfur dichloride, also known as sulfur(II) chloride, is a . Its formula is SCl2. It contains in its +2 . It also contains .