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Muscles are torn down, and glycogen stores are depleted during intense workouts, which is why post workout, you need to feed your muscles with what it needs - both protein and carbs - not just protein alone. Studies show that carbs are stored as glycogen 125% more efficiently directly after working out than any other time during the day. This is also when protein synthesis is also increased.
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Put it this way, whey protein is the fastest absorbing protein, taken by itself, more of it gets burnt for energy than used for protein synthesis, now if you take this with a carb with a high glycemic index (fast absorbing), the whey is put to better use for protein synthesis, and the carbs are used to replenish glycogen stores.