meta-Chlorophenol, CAS Number: 108-43-0

and into Dimethyl trichlorophenyl phosphorothioate, a systemic agent effective against grubs in cattle; and into 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T) or 2,4,5-Trichlorophenoxypropionic acid (2,4,5-TCPPA), both widely used as weed killers.

4-Chloro-3-methylphenol CAS 59-50-7 | 802295

10% NaOHsolution and again with water.A mixture ofo-chloro phenol ..


The facility with which the aromatic ring of phenols and phenol ethers undergoes electrophilic substitution has been noted. Two examples are shown in the following diagram. The first shows the Friedel-Crafts synthesis of the food preservative BHT from para-cresol. The second reaction is interesting in that it further demonstrates the delocalization of charge that occurs in the phenolate anion. Carbon dioxide is a weak electrophile and normally does not react with aromatic compounds; however, the negative charge concentration on the phenolate ring enables the carboxylation reaction shown in the second step. The sodium salt of salicylic acid is the major ptoduct, and the preference for ortho substitution may reflect the influence of the sodium cation. This is called the Kolbe-Schmidt reaction, and it has served in the preparation of aspirin, as the last step illustrates.

Products >> Phenol derivatives >> 4-Chloro-m-cresol ..

As with the alcohols, the phenolic hydroxyl hydrogen is rather easily replaced by other substituents. For example, phenol reacts easily with acetic anhydride to give phenyl acetate. Likewise, the phenolate anion is an effective nucleophile in SN2 reactions, as in the second example below.

Mono Chloro Phenol - Manufacturers, Suppliers & …

Compounds in which a hydroxyl group is bonded to an aromatic ring are called phenols. The chemical behavior of phenols is different in some respects from that of the alcohols, so it is sensible to treat them as a similar but characteristically distinct group. A corresponding difference in reactivity was observed in comparing aryl halides, such as bromobenzene, with alkyl halides, such as butyl bromide and tert-butyl chloride. Thus, nucleophilic substitution and elimination reactions were common for alkyl halides, but rare with aryl halides. This distinction carries over when comparing alcohols and phenols, so for all practical purposes substitution and/or elimination of the phenolic hydroxyl group does not occur.

Phenol, 4-amino-3-chloro- supply

The first problem concerns the relative acidity of different functional groups. The last asks you to draw the product of a reaction selected from 48 possible combinations of alcohols or phenols and selected reagents.

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The Birch Reduction
Another way of adding hydrogen to the benzene ring is by treatment with the electron rich solution of alkali metals, usually lithium or sodium, in liquid ammonia. To see examples of this reaction, which is called the Birch Reduction, .